# Ar/Ar dating of samples from Aluto and Corbetti volcanoes, Ethiopia (NERC grant NE/L013932/1)

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## Potassium-Argon Dating Methods

However, it is well established that volcanic rocks e. If so, then the K-Ar and Ar-Ar “dating” of crustal rocks would be similarly questionable. Thus under certain conditions Ar can be incorporated into minerals which are supposed to exclude Ar when they crystallize. Patterson et al.

When measured, all 40Ar* in a rock is assumed to have been produced by in situ radioactive decay of 40K within the rock since it formed. However, it is well.

In the diagram below I have drawn 2 different age spectra. The bottom, green spectrum is what we would expect to see if we had an ideal sample that has no excess-Ar, and the top, blue spectrum is what we might expect if the sample contained excess-Ar in fluid inclusions. The data for each of those 7 steps is represented by one of the 7 boxes on the diagram. On an age spectrum, the ages are plotted as boxes to show how big the errors are on each step.

On the green diagram I have also drawn age data points and error bars at the end of each box to help you visualise it better. Hopefully you can see that, on the green diagram, all the ages are very similar, but on the blue diagram the first three steps give older Ar-ages. In this situation we can use all of the data to calculate a more precise age for the sample — that is represented by the dotted black line.

But what if there are fluid inclusions in the sample that add excess-Ar, like we discussed in the last blog? Well, it is quite common for these inclusions to break down and release their gas at relatively low temperatures. This means that the ages we calculate from the first few temperature steps will be older than the later steps that release gas from the crystal lattice. You can see how this typically manifests in the blue age-spectrum, where the first 3 steps have older ages than the later steps.

## Ar-Ar Dating Methods

Arguably the most versatile of all the modern dating methods uses the decay of an isotope of potassium into an isotope of argon. The most useful version of this dating method employs nuclear reactions to convert potassium, calcium and chlorine into a variety of argon isotopes. This so-called argon-argon dating method not only provides valuable time information but also gives us important chemical signals from the sample being analyzed. With investigators being able to analyze smaller and smaller mineral samples, it is possible to see that even the most pristine looking mineral often has tiny imperfections, which can be detected and interpreted using the extra chemical data available with the argon-argon method.

Previously, to provide constraints on the formation ages of quartz-bearing hydrothermal ore deposits, Ar–Ar dating for fluid inclusions and trapped.

Potassium-argon dating , method of determining the time of origin of rocks by measuring the ratio of radioactive argon to radioactive potassium in the rock. This dating method is based upon the decay of radioactive potassium to radioactive argon in minerals and rocks; potassium also decays to calcium Thus, the ratio of argon and potassium and radiogenic calcium to potassium in a mineral or rock is a measure of the age of the sample. The calcium-potassium age method is seldom used, however, because of the great abundance of nonradiogenic calcium in minerals or rocks, which masks the presence of radiogenic calcium.

On the other hand, the abundance of argon in the Earth is relatively small because of its escape to the atmosphere during processes associated with volcanism. The potassium-argon dating method has been used to measure a wide variety of ages. The potassium-argon age of some meteorites is as old as 4,,, years, and volcanic rocks as young as 20, years old have been measured by this method.

Potassium-argon dating. Info Print Cite.

## Potassium-argon dating

Skip to search form Skip to main content You are currently offline. Some features of the site may not work correctly. DOI: The aim of this chapter is to present the K-Ar and Ar-Ar dating techniques in the context of noble gas studies, since there are already several recent texts on K-Ar and Ar-Ar dating Dickin ; McDougall and Harrison

The 40Ar/39Ar technique is a relative dating method, that is, ages are referenced back to a mineral standard of ‘known’ age. Mineral standards of.

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## Potassium-Argon and Argon-Argon Dating of Crustal Rocks and the Problem of Excess Argon

Potassium—argon dating. An absolute dating method based on the natural radioactive decay of 40 K to 40 Ar used to determine the ages of rocks and minerals on geological time scales. Argon—argon dating. A variant of the K—Ar dating method fundamentally based on the natural radioactive decay of 40 K to 40 Ar, but which uses an artificially generated isotope of argon 39 Ar produced through the neutron irradiation of naturally occurring 39 K as a proxy for 40 K.

For this reason, the K—Ar method is one of the few radiometric dating techniques in which the parent

Soon after the discovery of radioactive potassium, the K-Ar dating technique was one of the earliest isotope dating techniques. Radioactive potassium is easily.

Ar-Ar dating: principles Ar-Ar dating is the workhorse in geochronology and allows dating of samples that range in age from the origin of the solar system up to a few hundred thousand years. The basic principle of this dating method is accumulation of radiogenic 40 Ar from 40 K by an electron-capture decay. The method is thus a modified K-Ar dating method and allows dating of all types of samples that contain reasonable amounts of potassium.

Particularly usefull are K-rich minerals such as K-feldspar, micas and hornblende. The half-life of 40 K is 1. Age determinations require the knowledge of parent and daughter isotope abundances within a sample, i. To circumvent the necessity to measure K in a sample, rocks or minerals to be dated by the Ar-Ar method were irradiated by fast neutrons within a nuclear reactor. The produced 39 Ar is then a measure of the K content in a sample at a given neutron flux.

After irradiation, the Argon is thermally extracted from the samples within an ultra-high vacuum UHV system by using either an IR laser or a furnace system.

## Ar-Ar Geochronology Laboratory

This laser is used to ablate areas of sample a few 10s of microns across and extracts small gas samples for geochronology or noble gas analyses. Another major use of this system has been the determination of the diffusion and partition paramaters for noble gases from He to Xe laboratory experiments, and helium diffusion in apatite. The resulting gas is extracted via an all metal extraction line and cleaned by 3 AP getters.

Ar-Ar dating of muscovite and biotite from high-grade schist and pelitic gneiss cored at Ocean Drilling Program Site in the Alboran Sea yield cooling ages in.

Most people envision radiometric dating by analogy to sand grains in an hourglass: the grains fall at a known rate, so that the ratio of grains between top and bottom is always proportional to the time elapsed. In principle, the potassium-argon K-Ar decay system is no different. Of the naturally occurring isotopes of potassium, 40K is radioactive and decays into 40Ar at a precisely known rate, so that the ratio of 40K to 40Ar in minerals is always proportional to the time elapsed since the mineral formed [ Note: 40K is a potassium atom with an atomic mass of 40 units; 40Ar is an argon atom with an atomic mass of 40 units].

In theory, therefore, we can estimate the age of the mineral simply by measuring the relative abundances of each isotope. Over the past 60 years, potassium-argon dating has been extremely successful, particularly in dating the ocean floor and volcanic eruptions. K-Ar ages increase away from spreading ridges, just as we might expect, and recent volcanic eruptions yield very young dates, while older volcanic rocks yield very old dates.

Though we know that K-Ar dating works and is generally quite accurate, however, the method does have several limitations. First of all, the dating technique assumes that upon cooling, potassium-bearing minerals contain a very tiny amount of argon an amount equal to that in the atmosphere.

## Ar-Ar Dating and Noble Gas Mass Spectrometry

Western Australian Argon Isotope Facility. The Ar technique can be applied to any rocks and minerals that contain K e. Typically, we need to irradiates the sample along with known age standards with fast neutrons in the core of a nuclear reactor. This process converts another isotope of potassium 39 K to gaseous 39 Ar. This allows the simultaneous isotopic noble gas measurement of both the parent 39 Ar K and daughter 40 Ar isotopes in the same aliquot.

Because the reported age of an analyzed sample is dependent on the age of the co-irradiated monitor standard(s), Ar/Ar dating is a relative dating technique.

Isotopic dating is a critical tool in the earth sciences as it adds the essential dimension of time to a myriad of geological processes. Arguably the most versatile of all the modern dating methods uses the decay of an isotope of potassium into an isotope of argon. The most useful version of this dating method employs nuclear reactions to convert potassium, calcium and chlorine into a variety of argon isotopes.

This so-called argon-argon dating method not only provides valuable time information but also gives us important chemical signals from the sample being analyzed. With investigators being able to analyze smaller and smaller mineral samples, it is possible to see that even the most pristine looking mineral often has tiny imperfections, which can be detected and interpreted using the extra chemical data available with the argon-argon method.

However, by only looking at elements near argon in mass, there is a significant blind spot because other important major elements cannot normally be measured. This project is an attempt to extend the versatility of the argon-argon dating method by using neon isotopes which are created by nuclear reactions with sodium, magnesium and fluorine. The production of significant quantities of neon isotopes has been demonstrated and the project will do the important work of calibrating the system so that other researchers can adopt this extension to the method.

## K-Ar and Ar-Ar Dating

Raw data of the argon isotopes have been uploaded as the electronic supplementary material. Fluid inclusions in hydrothermal quartz in the 2. To constrain the origin of the fluid and the quartz precipitation age, we conducted Ar—Ar dating for the quartz via a stepwise crushing method. The obtained argon isotopes show two or three endmembers with one or two binary mixing lines as the crushing proceeds, suggesting that the isotopic compositions of these endmembers correspond to fluid inclusions of each generation, earlier generated smaller 40 Ar- and K-rich inclusions, moderate 40 Ar- and 38 Ar Cl neutron-induced 38 Ar from Cl -rich inclusions and later generated larger atmospheric-rich inclusions.

Considering the fluid inclusion generations and their compositions, the hydrothermal system was composed of crustal fluid and magmatic fluid without seawater before the beginning of a small amount of seawater input to the hydrothermal system.

40Ar/39Ar dating has the capability for unsurpassed precision and is applicable to the broadest range of geologic environments and time scales of any.

Time is a fundamental parameter in the Earth Sciences whose knowledge is essential for estimating the length and rate of geological processes. The 40 Ar- 39 Ar method, variant of the K-Ar method, is based on the radioactive decay of the naturally occurring parent 40 K half-life 1. The 40 Ar- 39 Ar method, applied to K-bearing systems minerals or glass , represents one of the most powerful geochronological tools currently available to constrain the timing of geological processes.

It can be applied to a wide range of geological problems and to rocks ranging in age from a few thousand years to the oldest rocks available. The development of the laser extraction technique has expanded fields of application, including among others:. Gianfranco di Vincenzo Ph. The greatest advantage of the laser extraction method over the conventional furnace extraction is that it permits analysis of very small samples down to a few micrograms or even less in same cases.

## Potassium-argon (K-Ar) dating

The extensive calibration and standardization procedures undertaken ensure that the results of analytical studies carried out in our laboratories will gain immediate international credibility, enabling Brazilian students and scientists to conduct forefront research in earth and planetary sciences. Modern geochronology requires high analytical precision and accuracy, improved spatial resolution, and statistically significant data sets, requirements often beyond the capabilities of traditional geochronological methods.

The fully automated facility will provide high precision analysis on a timely basis, meeting the often rigid requirements of the mineral and oil exploration industry. We will also discuss future developments for the laboratory. The project enabled importing the most advanced technology for the implementation of this dating technique in Brazil. Funding for the acquisition of instrumentation i.

Geochemical analysis of and Ar/Ar dating for volcanic samples from Aluto volcano, Ethiopia (NERC grant NE/L/1). Published by: British Geological.

The potassium-argon K-Ar isotopic dating method is especially useful for determining the age of lavas. Developed in the s, it was important in developing the theory of plate tectonics and in calibrating the geologic time scale. Potassium occurs in two stable isotopes 41 K and 39 K and one radioactive isotope 40 K. Potassium decays with a half-life of million years, meaning that half of the 40 K atoms are gone after that span of time.

Its decay yields argon and calcium in a ratio of 11 to The K-Ar method works by counting these radiogenic 40 Ar atoms trapped inside minerals.